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TKN Calculator

The organic nitrogen split, total nitrogen, and — the part that actually matters — the oxygen and alkalinity your nitrifiers will demand once the organic fraction hydrolyses inside your plant.

Nitrogen Balance & Load
mg/L as N
mg/L as N
mg/L as N
mg/L CaCO₃
MGD
mg/L as N
17
mg/L organic nitrogen
38% organic
Org N = TKN − NH₃-N  ·  TN = TKN + NO₂-N + NO₃-N  ·  O₂ = 4.57 × TKN  ·  Alkalinity destroyed = 7.14 × TKN  ·  recovered = 3.57 × NO₃-N denitrified

Why the Load Is Calculated on TKN

Organic nitrogen hydrolyses to ammonia inside your process. It arrives as protein and leaves the primary clarifier as ammonia demand you didn't count at the headworks.

So the oxygen your blowers have to supply, and the alkalinity your process will consume, are driven by TKN — not by influent ammonia. A plant sizing aeration or chemical alkalinity addition off ammonia alone runs short on high-organic-nitrogen days: heavy septage receipt, an industrial protein load, high solids.

Per mg/L of nitrogenValue
Oxygen consumed, nitrification4.57 mg/L
Alkalinity destroyed, nitrification7.14 mg/L as CaCO₃
Alkalinity recovered, denitrification3.57 mg/L as CaCO₃
Minimum effluent alkalinity to hold50 mg/L as CaCO₃

Reading the Organic Split

PatternSuggests
High ammonia fractionFresh domestic wastewater, short collection system, or significant sidestream return. Nitrogen is already in the form your nitrifiers use.
High organic fractionLonger collection time not yet hydrolysed, industrial protein load, high solids, or septage receipt. That nitrogen becomes ammonia demand on a delay.
Sudden shift toward organicInvestigate — a slug of protein-rich waste or septage arrived.
The split moves in the bottle. EPA Method 351.1 warns that even preserved with acid and refrigerated, organic nitrogen can convert to ammonia during storage. Total TKN is unaffected — but your calculated organic nitrogen is wrong, because the separately measured ammonia has risen. Run both determinations on the same sample, handled the same way, as soon as possible.

The Full TKN Guide

What the test captures and what EPA says it misses, the four methods and their ranges, the preservation trap, the sidestream problem, and why soluble non-biodegradable organic nitrogen sets a floor on total nitrogen removal.

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